Posted 3 May 2012
Stainless steel can provide excellent service underground. It is stronger than polymers and copper and its resistance to chlorides and acidic acids is significantly better than carbon or galvanised steels.
The performance of stainless steel buried in soil depends on the nature of the buried environment. If the soil has a high resistivity and is well drained, performance can be excellent even in conditions where other unprotected materials suffer degradation.
The Nickel Institute guidelines for burial of bare stainless steel in soil require:
- No stray currents (see below) or anaerobic bacteria
- pH greater than 4.5
- Resistivity greater than 2000 ohm.cm.
Additional recommendations include the absence of oxidising manganese or iron ions, avoidance of carbon-containing materials and ensuring a uniform, well drained fill. If the guidelines are breached, then either a higher resistivity is required, i.e. measures to lower moisture or salts and ensure resistivity exceeds 10,000 ohm.cm, or else additional protective measures may be required.
In comparison, the piling specification (AS 2159) guidelines for mild steel require a pH greater than 5 and resistivity greater than 5000 ohm.cm for soils to be non-aggressive. It is rare for bare mild steel to be buried, i.e. typical specifications include a wrap or coating possibly with a cathodic protection system.
- Uniform soil packing is required as variable compaction can induce differential aeration effects.
- Avoid organic materials in the fill around buried stainless steel as they can encourage microbial attack.
- Avoid carbon-containing ash in contact with metals in soils. Localised galvanic attack of the metal can occur.
- Oxygen access is critical. Having good drainage and sand backfill provides this. A sand-filled trench dug through clay may become a drain and it is not appropriate. Stainless steels generally retain their passive film provided there is at least a few ppb of oxygen, i.e. 1000 times less than the concentration in water exposed to air.
- Chlorides are the most frequent cause of problems with stainless steels. In soils, the level of chlorides vary with location, depth and, in areas with rising salinity, with time. High surface chlorides may also occur with evaporation. This is a problem for all metals although stainless steels are not usually subject to structural failure.
The general guidelines for immersed service are that in neutral environments at ambient temperatures and without crevices, 304/304L may be used up to chloride levels of 200ppm, 316/316L up to about 1000ppm chloride and duplex (2205) up to 3600ppm chloride. The super duplex alloys (PRE>40) and the 6% molybdenum super austenitic stainless steels are resistant to seawater levels of chloride, i.e. approximately 20,000ppm. These guidelines are easy to apply in aqueous solutions.
Soil tests for chlorides may not exactly match actual exposure conditions in the soil. Actual conditions may be more (or less) severe than shown by the tests. The difference is calculable but in practice, the aqueous limits can be used as general guidelines. More specific recommendations, based on published guidelines, are provided in Table 1.
It may seem redundant to assess both chlorides and resistivity. Both are required as the resistivity is primarily affected by water content and if it is low, then quite high chlorides could be tolerated – as seen by the choice of 304/304L in high chloride/high resistivity conditions. Despite these recommendations, most Australian practice is to use 316/316L or equivalent, primarily because of variable soils.
- Good drainage and uniform, clean backfill are essential for bare stainless.
- Duplex or super duplex could be replaced with appropriate austenitics and 304/304L could be replaced with a lean duplex.
- Ferritic stainless steels of similar corrosion resistance (usually classified by Pitting Resistance Equivalent [PRE]) could also be used underground.
Potential acid sulphate soils are widespread, particularly in coastal marine areas as described in http://www.derm.qld.gov.au/land/ass/index.html. Once disturbed and drained, which also allows oxygen access, such soils typically become more acidic than pH 4 and will attack metals (although stainless steels will be less readily attacked than other metals). Detailed assessment is required if using metals in such an environment as the effect of other aggressive ions is likely to be more severe at low pH.
- Properly specified stainless steel can provide the longest service underground. It is strong compared to plastics and copper, and is more reliably corrosion resistant than carbon steel.
- Table 1 guides grade choice for soil conditions.
- Normal fabrication practices apply: welds must be pickled and carbon steel contamination avoided.
- Pipelines must be buried in clean sand or fine, uniform fill in a self-draining trench that avoids stagnant water. Organic or carbonaceous fill must be avoided.
The Nickel Institute published a five year Japanese study in 1988 (#12005) showing 304 and 316 gave good service in buried soil, although vertically buried pipes did suffer some minor pitting and staining apparently due to differential aeration effects.
- NI #12005 describes a five year burial exposure in Japan at 25 sites with highly varied corrosivity. After five years in marine sites, horizontal 304 pipes showed no pitting but some crevice attack under vinyl wrap. Only one 316 pipe showed any attack.
- Vertical 304 pipe suffered attack near the base at some sites apparently due to differential aeration effects.
- An Idaho study of a 33-year NIST burial found 12% Cr martensitics perforated. The ‘lake sand’ site had high ground water with pH 4.7 at recovery. Sensitised 304 was attacked worse than annealed but both suffered attack along the rolling direction from edges.
- 316 was not attacked even if sensitised.
As noted, duplex stainless steel of similar corrosion resistance (PRE) to 304 and 316, respectively, would be expected to provide similar results when buried.
On a more practical level, there are several common approaches that are used when burying stainless steel:
- Wrap the stainless steel pipe in a protective material, such as a petrolatum tape, prior to burial. If the wrapping is effective (typically an overlap no less than 55% of the wrap width is specified), then the nature of the external surface of the buried pipe is of no consequence. In this case, stainless steel is only used for its internal corrosion resistance, i.e. its resistance to corrosion by the fluid which the pipe is carrying. Some authorities prohibit this practice because of concerns that damage to the wrap could cause a perforating pit in severe environments.
- Ensure that the soil environment surrounding the buried stainless steel is suitable for this application. In this case, the trench is dug so that it is self-draining, without there being areas where stagnant water can accumulate in contact with the buried pipe. The stainless steel pipe is then placed on a sand or crushed aggregate bed and covered by similar material. Under these circumstances, 316 grade stainless steel can be quite a suitable choice. US practice is to use 304 but Australian soils are quite variable and there have been mixed experiences with 304.
- Above ground sections of pipework are often stainless steel as they are at risk of mechanical damage while underground pipework is polymeric - polyethylene (PE) or fibre reinforced plastic (FRP) - despite the risk of damage due to soil movement.
In all of these cases, the assumption is that the stainless steel has been fabricated to best practice. This includes pickling of welds (or mechanical removal of heat tint and chromium depleted layer followed by passivation to dissolve sulphides) and ensuring that contamination by carbon steel has been prevented. It is also assumed that the buried stainless steel does not have stickers or heavy markings that could cause crevices and lead to attack.
All buried metals, including stainless steels, are at risk if there are stray currents from electrically driven transport, incorrectly installed or operated cathodic protection systems, or earthing faults in switchboards. Stray current corrosion can be identified as it causes localised general loss rather than pitting. It is also very rapid.
WHAT TEST METHODS ARE USED?
There are Australian and ASTM standards giving basic measurements of resistivity on site with 4 pin Wenner probes or in a soil box in the laboratory. More detailed checking includes water content, chlorides, organic carbon or Biological Oxygen Demand (BOD), pH and redox (or Oxidation Reduction Potential [ORP]) potential – which assess microbial attack risk but also captures the effect of oxidising ions and dissolved oxygen. Most of these test methods are covered in “Soil Chemical Methods: Australasia” written by George E Rayment and David J Lyons and published by CSIRO.
Natural soils are a mixture of coarse pebbles, sand of increasing fineness through to silts and clays where the particles are less than 5 µm in diameter. Some of the particles contain soluble salts that, if mixed with water, are likely to be corrosive. Normally, soils also contain organic material from decaying plants or ash, which can provide nutrients for microbial activity or galvanic effects, respectively.
If water is present in the soil, corrosion can take place. Metals below the water table can corrode (following the rules for immersed service). However if the soil is well compacted so oxygen cannot gain access or corrosion products cannot diffuse away, then corrosion would be stifled - even for carbon steel. Above the water table, moisture comes from percolating rain, which will, over time, leach away soluble corrosives and make the soil less aggressive. This also means that in dry climates, salts may accumulate and when there is rain, the run-off or percolating water is very aggressive. Deposited salts can also be a problem in marine zones almost regardless of rainfall.
Most of the moisture above the water table is bound to particles but if there is sufficient water content, typically more than about 20%, enough water is free to wet buried metals.
Image pictured is the Appin Sewerage Treatment Plant, NSW. Fabricated and installed by ASSDA member and Accredited Fabricator Roladuct Spiral Tubing Pty Ltd using 316 grade stainless steel. Image courtesy of Roladuct Spiral Tubing Pty Ltd.
This technical article is featured in Australian Stainless magazine, issue 51.